Chains of atoms move at lightning speed inside metals

October 15, 2019 by Monica Westman Svenselius, Linköping University
Mass transport in titanium. Credit: Linköping University

A phenomenon that has previously been seen when researchers simulate the properties of planet cores at extreme pressures has now also been observed in pure titanium at atmospheric pressure. Chains of atoms dash around at lightning speeds inside the solid material.

"The phenomenon we have discovered changes the way we think about mass transport in metals. It explains properties of metals that we have, until now, not been able to understand. It's too early to say what this means in practical terms, but the more we know about how materials function in different conditions, the better possibilities we have to develop materials with new or improved properties," says Davide Sangiovanni, researcher in the Division of Theoretical Physics at LIU and principal author of an article that has been published in Physical Review Letters.

Crystal structure

In such as metals, the atoms are arranged in a well-organized , at definite distances from each other. Diffusion typically occurs as isolated "rare" hops of atoms into vacancies (crystal defects). However, for some materials—such as fast ion conductors at elevated temperatures, or water ("superionic ice") and iron at the found in planetary-cores—long chains of atoms/ions can suddenly start to move at surprisingly high speed as an entity. The process occurs on time scales of picoseconds or nanoseconds, and does not affect the crystal structure. The phenomenon is sometimes called "concerted ," "superionic diffusion" or "liquid-like diffusion," and has been described in a number of theoretical papers.

The most exciting discovery that he has made, however, together with colleagues at Linköping University and universities in Germany and Russia, is that the same diffusion can take place in the cubic phase of pure titanium, at normal atmosphere pressure and at a temperature below the melting point.

Concerted diffusion

Titanium, zirconium and hafnium, which are all in Group IVB of the periodic table, have several characteristic properties that researchers have not been able to explain—until now.

"In the article, we show that the anomalous properties of Group IVB metals in their cubic structure originate from concerted diffusion, in which the atomic chains wriggle through the solid crystal," says Davide Sangiovanni.

More information: D. G. Sangiovanni et al. Superioniclike Diffusion in an Elemental Crystal: bcc Titanium, Physical Review Letters (2019). DOI: 10.1103/PhysRevLett.123.105501

Provided by Linköping University