Wiggling atoms switch the electric polarization of crystals

Wiggling atoms switch the electric polarization of crystals
(a) Stationary electron density in the grey plane shown in Fig. 1. (b) Change of electron density at a delay time of 2.8 picoseconds (ps) after excitation of the ammonium sulfate crystallites. The circles mark the atomic positions, the black arrows indicate the transfer of electronic charge between one of the oxygen atom and the SO3 group of a single sulfate ion. The vibrational displacements of the atoms are smaller than the line thickness of the circles and, thus, invisible on this length scale. (c) The reverse charge transfer occurs at a delay time of 3.9 ps. Credit: MBI Berlin

Ferroelectric crystals display a macroscopic electric polarization, a superposition of many dipoles at the atomic scale that originate from spatially separated electrons and atomic nuclei. The macroscopic polarization is expected to change when the atoms are set in motion but the connection between polarization and atomic motions has remained unknown. A time-resolved X-ray experiment has revealed that tiny atomic vibrations shift negative charges over a distance 1000 times larger between atoms and switch the macroscopic polarization on a time scale of a millionth of a millionth of a second.

Ferroelectric materials have applications in electronic sensors, memory and switching devices. In this context, fast, controlled changes of their electric properties are essential for implementing specific functions efficiently. This calls for understanding the connection between atomic structure and macroscopic electric properties, including the physical mechanisms governing the fastest possible dynamics of macroscopic electric polarizations.

Researchers from the Max Born Institute in Berlin have now demonstrated how modulate the macroscopic electric of the prototype ferroelectric ammonium sulphate [Fig. 1] on a time scale of a few picoseconds (1 picosecond (ps) = 1 millionth of a millionth of a second). In the current issue of the journal Structural Dynamics, they report an ultrafast X-ray experiment that allows for mapping the motion of charges over distances on the order of the diameter of an atom (10-10 m = 100 picometers) in a quantitative way. In the measurements, an ultrashort excitation pulse sets the atoms of the material, a powder of small crystallites, into . A time-delayed hard X-ray pulse is diffracted from the excited sample and measures the momentary atomic arrangement in form of an X-ray powder diffraction pattern. The sequence of such snapshots represents a movie of the so-called electron-density map from which the spatial distribution of electrons and atomic vibrations are derived for each instant in time ([Fig. 2]).

Wiggling atoms switch the electric polarization of crystals
The upper panel shows a change of the S-O bond length as a function of the delay time. The maximum change of 0.1 pm is 1000 times smaller than the bond length itself, i.e., the atomic motions cannot be observed in Fig. 2. Middle panel: Charge transfer from one oxygen atom to the SO3 group of the sulfate ion (left black arrows in Fig. 2) as a function of delay time. Lower panel: Change of the macroscopic polarization P along the c axis which is the sum of all microscopic dipole changes of the local S-O dipoles within the sulfhate ions (red and blue arrows in Fig. 1 bottom right). Credit: MBI Berlin

The electron density maps show that electrons move over distances of 10-10 m between atoms which are more than a thousand times larger than their displacements during the vibrations [Fig. 3]. This behavior is due to the complex interplay of local electric fields with the polarizable electron clouds around the and determines the momentary electric dipole at the atomic scale. Applying a novel theoretical concept, the time-dependent charge distribution in the atomic world is linked to the macroscopic electric polarization [Fig. 3]. The latter is strongly modulated by the tiny atomic vibrations and fully reverses its sign in time with the . The modulation frequency of 300 GHz is set by the frequency of the atomic vibrations and corresponds to a full reversal of the microscopic polarization within 1.5 ps, much faster than any existing ferroelectric switching device. At the surface of a crystallite, the maximum electric polarization generates an electric field of approximately 700 million volts per meter.

Wiggling atoms switch the electric polarization of crystals
This is a crystal lattice of ferroelectric ammonium sulfate [(NH4)2SO4] with tilted ammonium (NH4+) tetrahedra (nitrogen: blue, hydrogen: white) and sulfate (SO42-) tetrahedra (sulfur: yellow, oxygen: red). The green arrow shows the direction of macroscopic polarization P. Blue arrows: local dipoles between sulphur and oxygen atoms. The electron density maps shown in the bottom left panel, in Fig. 2, and the movie are taken in the plane shown in grey. Bottom left: Stationary electron density of sulfur and oxygen atoms, displaying high values on the sulfur (red) and smaller values on the oxygens (yellow). Bottom right: Change of local dipoles at a delay time of 2.8 picoseconds (ps) after excitation of the ammonium sulfate crystallites. An anisotropic shift of charge reduces the dipole pointing to the right and increases the other 3 dipoles. Credit: MBI Berlin

The results establish time-resolved ultrafast X-ray diffraction as a method for linking charge dynamics to macroscopic electric properties. This novel strategy allows for testing quantum-mechanical calculations of electric properties and for characterizing a large class of polar and/or ionic materials in view of their potential for high-speed electronics.

More information: Christoph Hauf et al, Soft-mode driven polarity reversal in ferroelectrics mapped by ultrafast x-ray diffraction, Structural Dynamics (2018). DOI: 10.1063/1.5026494

Provided by Forschungsverbund Berlin

Citation: Wiggling atoms switch the electric polarization of crystals (2018, April 13) retrieved 28 March 2024 from https://phys.org/news/2018-04-wiggling-atoms-electric-polarization-crystals.html
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