Researchers create blackest material ever made

Researchers create blackest material ever made
Optical black body, the fabrication of which occurs via seeded growth of Au nanospheres from Au nanorods. a, Low-magnification TEM image of a realized sample. b, TEM image of a single nanostructure. c, HRTEM image near the kissing point between the nanosphere and the nanorod. Credit: (c) 2015 Nature Nanotechnology (2015) doi:10.1038/nnano.2015.228

(Phys.org)—A team of researchers at King Abdulla University of Science and Technology in Saudi Arabia has made the blackest material ever created by human beings. As they note in their paper published in Nature Nanotechnology, the idea for the material came from the all-white cyphochilus beetle.

As the researches also note, it is likely impossible to create the perfect black material that absorbs all of the energy that strikes it, and then emits it without any loss of energy. Still, scientists would like to come closer because it is believed that such materials could help in creating better or more efficient devices, such as solar collectors. In this new effort, the team bested the blackness of previous materials using carbon nanotubes by emulating what they found when studying the all-white cyphochilus beetle. The result was a an extremely tiny nanoparticle rod resting on an equally tiny nanoparticle sphere (30 nm diameter), which was able to absorb approximately 98 to 99 percent of the light in the spectrum between 400 and 1,400 nm, which meant that it is able to absorb approximately 26 percent more light than any other known material—and it does so from all angles and polarizations.

The researchers noted that the scales on the cyphochilus beetle—a photonic crystal structure—caused the beetle's shell to reflect light very efficiently. They took that idea and turned it on its head by inverting the structure and used the idea of chaotic energy harvesting to create the extremely black material—the surface of the structure is disordered, which creates a pattern of random pits, each consisting of infinitely long metallic waveguides. As a bonus, the material can be easily created and applied and used both in and out of liquids. Also, by firing a laser at it, they created a new type of light source that generated monochromatic emissions without the necessity of resonance.

The team notes that devices using such an application might be used for desalination projects, and, of course, in solar energy collecting systems, and perhaps in optical interconnects. They also suggest the material might even lead to using a wholly new approach in the design of such devices.

More information: Jianfeng Huang et al. Harnessing structural darkness in the visible and infrared wavelengths for a new source of light, Nature Nanotechnology (2015). DOI: 10.1038/nnano.2015.228

Abstract
Engineering broadband light absorbers is crucial to many applications, including energy-harvesting devices and optical interconnects. The performances of an ideal absorber are that of a black body, a dark material that absorbs radiation at all angles and polarizations. Despite advances in micrometre-thick films, the absorbers available to date are still far from an ideal black body. Here, we describe a disordered nanostructured material that shows an almost ideal black-body absorption of 98–99% between 400 and 1,400 nm that is insensitive to the angle and polarization of the incident light. The material comprises nanoparticles composed of a nanorod with a nanosphere of 30 nm diameter attached. When diluted into liquids, a small concentration of nanoparticles absorbs on average 26% more than carbon nanotubes, the darkest material available to date. By pumping a dye optical amplifier with nanosecond pulses of ∼100 mW power, we harness the structural darkness of the material and create a new type of light source, which generates monochromatic emission (∼5 nm wide) without the need for any resonance. This is achieved through the dynamics of light condensation in which all absorbed electromagnetic energy spontaneously generates single-colour energy pulses.

Journal information: Nature Nanotechnology

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